Services to Monitor

Services to Monitor

I just started to work with PMP and would like to monitor this server.

What services should I be monitoring & also what service should I monitor for the website, which right now is strictly internal.
Should it be just http, or does java have to be monitored also.

Also what about Postgres DB, I would like to monitor that.

Thanks
                New to ADManager Plus?

                  New to ADSelfService Plus?