prohibit applictaions

prohibit applictaions

hello 

I am new in desktop central manage engine.

I need to prohibit some applications that not applicable in my company, what should I do?? I go application control>block executable but it is just reporting and I can not configure it such as add new applications or delete applications or etc. my central engine is 10 version. 
would u please help me? do u have any document about the configuration? 

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