Alert on Login/Email Issue

Alert on Login/Email Issue

Is there a way to setup an alert if someone logs in as Administrator on 1 of my domains?  I do not want anyone using that logon and want to be notified when someone does.
Also, I configured Email and when I test to myself it works but when I put in an address that is a distribution group the email does not work.
 
Thanks,
David
 

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